Advanced Science (Apr 2025)

Laser‐Induced Graphene from Commercial Inks and Dyes

  • Alexander Dallinger,
  • Rachel Camerini,
  • Paola Parlanti,
  • Mauro Gemmi,
  • Sreenadh Thaikkattu Sankaran,
  • Marina Galliani,
  • Birgit Kunert,
  • Rodorico Giorgi,
  • Francesco Greco

DOI
https://doi.org/10.1002/advs.202412167
Journal volume & issue
Vol. 12, no. 14
pp. n/a – n/a

Abstract

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Abstract Laser‐induced graphene (LIG) has been so far obtained from polymer precursors and proposed for numerous applications, including various types of sensors and energy storage solutions. This study examines a radically different class of new precursors for LIG, distinct from polymers: inks and dyes. The identification of specific organic dyes present in commercial markers demonstrates that the aromatic structure, in conjunction with high thermal stability (residual weight > 20% at 800°C), are key factors for laser‐induced pyrolysis. Eosin Y is identified as an excellent LIG precursor, comparable with well‐known polyimide. The unique properties of dyes allow for dispersion in various media, such as acrylic binder. A dye concentration of 0.75 mol L−1 in acrylic binder results in a conductivity of 34 ± 20 S cm−1 for LIG. The composition and microstructure of LIG from dyes are thoroughly characterized, revealing peculiar features. A versatile “Paint & Scribe” methodology is introduced, enabling to integrate LIG tracks onto any wettable surface, and in particular onto printed and flexible electronics. A process for obtaining freestanding and transferrable LIG is demonstrated by dissolving acrylic paint in acetone and floating LIG in water. This advancement offers novel avenues for diverse applications that necessitate a transfer process of LIG.

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