Influence of Lithium Carbonate and Sodium Carbonate on Physical and Elastic Properties and on Carbonation Resistance of Calcium Sulphoaluminate-Based Mortars

Abstract

In this study, three different hardening accelerating admixtures (sodium carbonate, lithium carbonate and a blend of sodium and lithium carbonates) were employed to prepare calcium sulphoaluminate cement-based mortars. The workability, setting times, entrapped air, elasto-mechanical properties such as compressive strength and dynamic modulus of elasticity, free shrinkage, water absorption and carbonation rate were measured and mercury intrusion porosimetry were also performed. Experimental results show that a mixture of lithium carbonate and sodium carbonate acts as a hardening accelerating admixture, improving the early-age strength and promoting a remarkable pore structure refinement. Finally, sodium carbonate also reduces the water absorption, the carbonation rate and the shrinkage of mortars without affecting the setting times and the workability.

Keywords

• calcium sulphoaluminate cement
• supplementary cementitious materials
• carbonation
• lithium carbonate
• sodium carbonate