Phyto-assisted synthesis of magnetic NiFe2O4 nanocomposite using the Pulicaria gnaphalodes methanolic extract for the efficient removal of an antibiotic from the aqueous solution: a study of equilibrium, kinetics, isotherms, and thermodynamics

Abstract

In this research, the magnetic NiFe2O4 nanocomposite was synthesized using Pulicaria gnaphalodes methanolic extract and applied to remove penicillin G from aqueous solutions. The results of field emission scanning electron microscopy, X-ray powder diffraction, Fourier transform infrared, Vibrating-Sample Magnetometer (VSM), and energy-dispersive spectroscopy-mapping analyses showed that this nanocomposite was well synthesized with a size of approximately 50–70 nm. The maximum adsorption capacity of the magnetic NiFe2O4 nanocomposite was 22.95 mg/g under optimal conditions. In addition, the experimental data of penicillin G adsorption by the magnetic NiFe2O4 nanocomposite showed that ΔH and ΔS values were positive and ΔG was negative and were following the Temkin isotherm model with R2 = 0.99 and follows the pseudo-second-order kinetic model. HIGHLIGHTS The adsorption of penicillin G by NiFe2O4 was maximum in optimal conditions (pH = 3, nanocomposite dose: 0.3 g/L, penicillin G concentration: 30 g/L, contact time: 20 min, and time temperature: 313 K).; The thermodynamic study of the adsorption process showed that the values of ΔH and ΔS are positive and ΔG is negative.; Penicillin G adsorption by NiFe2O4 nanoparticles conforms to Temkin isotherm with R2 = 0.99.;

Keywords

• adsorption
• isotherm
• kinetic
• nanocomposite
• penicillin g
• thermodynamic