Acta Crystallographica Section E (Jul 2012)

(E)-4-Hydroxy-2-{[(2-phenylethyl)iminiumyl]methyl}phenolate

  • David Ortegon-Reyna,
  • Cesar Garcias-Morales,
  • Efren V. García-Báez,
  • Armando Ariza-Castolo,
  • Francisco J. Martínez-Martínez

DOI
https://doi.org/10.1107/S1600536812025408
Journal volume & issue
Vol. 68, no. 7
pp. o2075 – o2075

Abstract

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The title Schiff base compound, C15H15NO2, crystallized as the iminium–phenolate zwitterion. The H atom is localized on the imine N atom, forming a strong intramolecular hydrogen bond with the phenolate O atom, and giving rise to an S(6) ring motif. The molecule has an E conformation about the C=N bond. In the crystal, molecules are linked by O—H...O hydrogen bonds, forming chains propagating along [010]. There are also C—H...O interactions present.