IUCrData (Jan 2018)

N′-[(1E)-2,5-Dimethoxybenzylidene]pyridine-2-carbohydrazide

  • Mustafa R.Albayati,
  • Joel T. Mague,
  • Mehmet Akkurt,
  • Shaaban K. Mohamed,
  • Sahar M. I. Elgarhy

DOI
https://doi.org/10.1107/S2414314618001281
Journal volume & issue
Vol. 3, no. 1
p. x180128

Abstract

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The molecule of the title compound, C15H15N3O3, is twisted, with the dihedral angle between the pyridyl and benzene rings being 58.34 (6)°. In the crystal, amide-N—H...O(amide) and imine-C—H...O(amide) hydrogen bonds lead to zigzag (glide symmetry) chains extending along the c axis which are joined into layers parallel to the [100] direction by offset π–π stacking interactions between inversion-related benzene rings [centroid–centroid distance = 3.7468 (7) Å] and by C—H...π(pyridyl) interactions. Pyridyl rings protrude from the surfaces of the layers and partially intercalate with those of adjacent layers.

Keywords