Data supporting the in situ synthesis by organometallic method of Vulcan supported PdNi nanostructures for hydrogen evolution reaction in alkaline solution
J.J. de la Cruz-Cruz,
M.A. Domínguez-Crespo,
E. Ramírez-Meneses,
A.M. Torres-Huerta,
S.B. Brachetti-Sibaja,
A.E. Rodríguez-Salazar,
E. Pastor,
L.E. González-Sánchez
Affiliations
J.J. de la Cruz-Cruz
Instituto Politécnico Nacional, Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada, CICATA, Unidad Altamira, Carretera Tampico-Puerto Industrial, km 14.5, Altamira, Tamaulipas, CP 89600, México
M.A. Domínguez-Crespo
Instituto Politécnico Nacional, UPIIH, Ciudad del conocimiento y la cultura. Carretera Pachuca-Actopan km. 1+500 San Agustín Tlaxiaca, Hidalgo, México; Corresponding authors.
E. Ramírez-Meneses
Departamento de Ingeniería Química, Industrial y de Alimentos, Universidad Iberoamericana, Prolongación Paseo de la Reforma 880, Lomas de Santa Fe. C.P. 01219, Ciudad de México, México; Corresponding authors.
A.M. Torres-Huerta
Instituto Politécnico Nacional, UPIIH, Ciudad del conocimiento y la cultura. Carretera Pachuca-Actopan km. 1+500 San Agustín Tlaxiaca, Hidalgo, México
S.B. Brachetti-Sibaja
TecNM, Instituto Tecnológico de Cd. Madero. Ave. Primero de Mayo s/n Col. Los Mangos, C.P. 89440, Cd. Madero Tam., México
A.E. Rodríguez-Salazar
Instituto Politécnico Nacional, Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada Unidad-Querétaro, Cerro Blanco No. 141 Col. Colinas del Cimatario, C.P. 76090. Querétaro, Qro. México
E. Pastor
Instituto de Materiales y Nanotecnología, Departamento de Química, Universidad de La Laguna, A. 456, La Laguna, Santa Cruz de Tenerife Apartado Postal 38200, España
L.E. González-Sánchez
Departamento de Ingeniería Química, Industrial y de Alimentos, Universidad Iberoamericana, Prolongación Paseo de la Reforma 880, Lomas de Santa Fe. C.P. 01219, Ciudad de México, México
This document presents the supporting information for the evaluation of the role of Ni amount during the in situ synthesis of vulcan supported PdNi nanostructures using an organometallic approach for hydrogen evolution reaction in alkaline medium [1]. The data here presented included analysis of deconvolution during structural characterization, chemical composition and transmission electron microscopy. The information also contains complement data of cyclic voltammograms during activation in alkaline media. Supplement data of electrochemical impedance spectroscopy measurements at two different overpotentials (-100 and -300 mV) and temperatures on the onset potential for hydrogen evolution reaction (HER) are also showed in this paper. The files can be used as a reference to determinate the effect of adding different in situ amount of Ni to Pd/C catalysts in presence of 2 equivalents of hexadecylamine (HDA) in order to improve the electrochemical performance on HER using an adjusted organometallic method. The data provided in this article have not been previously published and are available to enable critical or extended analyses.
