Acta Crystallographica Section E (Feb 2009)

Bis(6-methoxy-2-{[tris(hydroxymethyl)methyl]iminomethyl}phenolato)copper(II) dihydrate

  • Bo Hu,
  • Bin Li,
  • Jianmin Dou,
  • Peihai Wei,
  • Xiutang Zhang

DOI
https://doi.org/10.1107/S1600536808043948
Journal volume & issue
Vol. 65, no. 2
pp. m151 – m152

Abstract

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In the title compound, [Cu(C12H16NO5)2]·2H2O, the CuII ion adopts a trans-CuN2O4 octahedral geometry arising from two N,O,O′-tridentate 6-methoxy-2-{[tris(hydroxymethyl)methyl]iminomethyl}phenolate ligands. The Jahn–Teller distortion of the copper centre is unusally small. In the crystal structure, O—H...O hydrogen bonds, some of which are bifurcated, link the component species.