Adsorptive performances and valorization of green synthesized biochar–based activated carbon from banana peel and corn cob composites for the abatement of Cr(VI) from synthetic solutions: Parameters, isotherms, and remediation studies

Abstract

This study intended to remove Cr(VI) from an aqueous synthetic solution employing synthesized biochar adsorbent from a blend of locally sourced banana peel, and corn cob biomass wastes. An equal ratio of the prepared powder was activated with ZnCl2 solution (1:1 wt basis) and carbonized for 2 h at 600 °C. The proximate analysis of the selected BP-CCAC@ZC3 biochar was conducted. Subsequently, its surface area, surface functions, and morphology were examined using BET analysis, FTIR, and SEM techniques, respectively. The proximate analysis of BP–CCAC@ZC3 showed a moisture content of 2.37 ± 0.80 %, an ash content of 8.07 ± 0.75 %, volatile matter of 19.38 ± 2.66 %, and fixed carbon of 70.18 %. It was found that the synthesized BP–CCAC@ZC3 had 432.149 m2/g of a specific area as per the BET surface area analysis. The highest efficiency for Cr(VI) removal was determined to be 97.92 % through adsorption batch tests using a dose of 0.4 g of BP-CCAC@ZC3, an initial Cr(VI) concentration of 20 mg/L, pH of 2, and 35 min contact time. Likewise, the adsorption process was effectively described by the Langmuir isotherm model, which had a high correlation coefficient (R2 = 0.9977) and a maximum adsorption capacity of 19.16 mg/g, indicating a monolayer adsorption mechanism. The BP-CCAC@ZC3 biochar exhibited reusability for up to four cycles with only a slight decrease in effectiveness, highlighting its potential for sustainable wastewater treatment. Overall, using corn cob and banana peel composites to synthesize activated carbon with ZnCl2 offers a promising method for effectively removing Cr(VI) containing wastewater.

Keywords

• Activated carbon
• Adsorption processes
• Hexavalent chromium
• Isotherm modeling
• Wastewater