Eurasian Chemico-Technological Journal (Jan 2008)
Nanodispersed Ni-Catalysts with Additives in Partial Oxidation of Methane
Abstract
Catalytic activity of Ni-Zn-surface-skeletal catalysts modified by Rh, Au, Ti, Mo and W in the reaction of methane partial oxidation has been studied. Influence of catalysts of conditions preparation on its catalytic activity was researched. It was shown that introduction of additives in Ni-Zn catalysts promote to increasing of activity in the process of methane partial oxidation to synthesis-gas and thermostability of skeletal Ni-catalysts thanks to the change of its faseous composition and the predominance of reduced form of Ni in catalysts structure.