Acta Crystallographica Section E (Sep 2010)

Bis[1-(2-ethoxyphenyl)-3-(4-nitrophenyl)triazenido]mercury(II)

  • Mohammad Kazem Rofouei,
  • Ehsan Fereyduni,
  • Jafar Attar Gharamaleki,
  • Giuseppe Bruno,
  • Hadi Amiri Rudbari

DOI
https://doi.org/10.1107/S1600536810031326
Journal volume & issue
Vol. 66, no. 9
pp. m1082 – m1082

Abstract

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In the title compound, [Hg(C14H13N4O3)2], the central Hg atom (site symmetry 2) is six-coordinated by two tridentate 1-(2-ethoxyphenyl)-3-(4-nitrophenyl)triazenide ligands through two N and one O atoms. The mononuclear complex molecules are connected into two parallel chains by intermolecular C—H...O hydrogen-bonding interactions. These chains are connected to each other by face-to-edge C—H...π interactions between the CH of the ethoxy groups and the aromatic rings, resulting in a two-dimensional architecture in the ac plane.