Materials (Nov 2020)

Thermal and Flame Retardant Properties of Phosphate-Functionalized Silica/Epoxy Nanocomposites

  • Il Jin Kim,
  • Jae Wang Ko,
  • Min Seop Song,
  • Ji Won Cheon,
  • Dong Jin Lee,
  • Jun Woo Park,
  • Seunggun Yu,
  • Jin Hong Lee

DOI
https://doi.org/10.3390/ma13235418
Journal volume & issue
Vol. 13, no. 23
p. 5418

Abstract

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We report a flame retardant epoxy nanocomposite reinforced with 9,10-dihydro-9-oxa-10-phosphaphenantrene-10-oxide (DOPO)-tethered SiO2 (DOPO-t-SiO2) hybrid nanoparticles (NPs). The DOPO-t-SiO2 NPs were successfully synthesized through surface treatment of SiO2 NPs with (3-glycidyloxypropyl)trimethoxysilane (GPTMS), followed by a click reaction between GPTMS on SiO2 and DOPO. The epoxy nanocomposites with DOPO-t-SiO2 NPs as multifunctional additive exhibited not only high flexural strength and fracture toughness but also excellent flame retardant properties and thermal stability, compared to those of pristine epoxy and epoxy nanocomposites with a single additive of SiO2 or DOPO, respectively. Our approach allows a facile, yet effective strategy to synthesize a functional hybrid additive for developing flame retardant nanocomposites.

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