EPJ Web of Conferences (Jan 2019)

Excited state vibrational coherence in a binuclear metal adduct: wave packet phase dependant molecular fragmentation under variation of ligand size

  • Kruppa Sebastian Volker,
  • Bäppler Florian,
  • Holzer Christof,
  • Dietrich Fabian,
  • Diller Rolf,
  • Klopper Wim,
  • Riehn Christoph

DOI
https://doi.org/10.1051/epjconf/201920509019
Journal volume & issue
Vol. 205
p. 09019

Abstract

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Ultrafast vibrational coherence with metal-metal stretching mode character is observed for phosphine-bridged d10-d10 complexes of different size, containing the binuclear [Ag2Cl]+ chromophore in an ion trap. Fragmentation pathways are governed by the wave packet's phase.