High CO Adsorption Performance of CuCl-Modified Diatomites by Using the Novel Method “Atomic Implantation”

Manh B. Nguyen; Tuyen V. Nguyen; Giang H. Le; Trang T. T. Pham; Khu Le Van; Giang T.T. Pham; Tung Ngoc Nguyen; Quang Vinh Tran; Tuan A. Vu

doi:10.1155/2021/9762578

Journal of Chemistry (Jan 2021)

High CO Adsorption Performance of CuCl-Modified Diatomites by Using the Novel Method “Atomic Implantation”

Manh B. Nguyen,
Tuyen V. Nguyen,
Giang H. Le,
Trang T. T. Pham,
Khu Le Van,
Giang T.T. Pham,
Tung Ngoc Nguyen,
Quang Vinh Tran,
Tuan A. Vu

Affiliations

Manh B. Nguyen: Institute of Chemistry, Vietnam Academy of Science and Technology (VAST), 18 Hoang Quoc Viet Street, Cau Giay, Ha Noi, Vietnam
Tuyen V. Nguyen: Institute of Chemistry, Vietnam Academy of Science and Technology (VAST), 18 Hoang Quoc Viet Street, Cau Giay, Ha Noi, Vietnam
Giang H. Le: Institute of Chemistry, Vietnam Academy of Science and Technology (VAST), 18 Hoang Quoc Viet Street, Cau Giay, Ha Noi, Vietnam
Trang T. T. Pham: Institute of Chemistry, Vietnam Academy of Science and Technology (VAST), 18 Hoang Quoc Viet Street, Cau Giay, Ha Noi, Vietnam
Khu Le Van: Faculty of Chemistry, Hanoi National University of Education (HNUE), Hanoi 100000, Vietnam
Giang T.T. Pham: Faculty of Chemical Technology, Hanoi University of Industry (HUI), 298 Minh Khai Bactuliem, Ha No. 100000, Vietnam
Tung Ngoc Nguyen: Center for Research and Technology Transfer, Vietnam Academy of Science and Technology (VAST), 18 Hoang Quoc Viet Street, Cau Giay, Ha Noi, Vietnam
Quang Vinh Tran: Institute of Chemistry, Vietnam Academy of Science and Technology (VAST), 18 Hoang Quoc Viet Street, Cau Giay, Ha Noi, Vietnam
Tuan A. Vu: Institute of Chemistry, Vietnam Academy of Science and Technology (VAST), 18 Hoang Quoc Viet Street, Cau Giay, Ha Noi, Vietnam

DOI: https://doi.org/10.1155/2021/9762578
Journal volume & issue: Vol. 2021

Abstract

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An atomic implantation method was used to modify diatomite with CuCl. The CuCl/diatomite samples were characterized by different techniques, including FTIR, XRD, BET, SEM-TEM, EDX, and CO-TPR. Characterization results revealed the formation of CuCl particles of 50–60 nm highly dispersed on diatomite surface. CO adsorption measurements showed that 2CuCl/diatomite exhibits the highest CO adsorption capacity among all CuCl-modified samples with diatomite. Its CO adsorption capacity of 2.96 mmol/g at 30°C is 10 times higher than that of unmodified diatomite (0.29 mmol/g). The CO adsorption on CuCl-modified diatomites was found to fit well with the Langmuir–Freundlich model.

Published in Journal of Chemistry

ISSN: 2090-9063 (Print); 2090-9071 (Online)
Publisher: Hindawi Limited
Country of publisher: United Kingdom
LCC subjects: Science: Chemistry
Website: https://onlinelibrary.wiley.com/journal/2962

About the journal