MIXED-VALENT TETRANUCLEAR MnIIMnIII3 COMPLEX WITH 1,3-DIAMINO-2-HYDROXYPROPANE-N,N’,N”,N”’-TETRAACETIC ACID

Masahiro Mikuriya; Nobuyuki Nagao; Satoshi Kurahashi; Atsushi Tabuchi; Seiki Tomohara; Motohiro Tsuboi; Daisuke Yoshioka; Hiroshi Sakiyama; Akira Fuyuhiro

Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry (Jun 2014)

MIXED-VALENT TETRANUCLEAR MnIIMnIII3 COMPLEX WITH 1,3-DIAMINO-2-HYDROXYPROPANE-N,N’,N”,N”’-TETRAACETIC ACID

Masahiro Mikuriya,
Nobuyuki Nagao,
Satoshi Kurahashi,
Atsushi Tabuchi,
Seiki Tomohara,
Motohiro Tsuboi,
Daisuke Yoshioka,
Hiroshi Sakiyama,
Akira Fuyuhiro

Affiliations

Masahiro Mikuriya: Department of Chemistry and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, Japan
Nobuyuki Nagao: Department of Chemistry and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, Japan
Satoshi Kurahashi: Department of Chemistry and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, Japan
Atsushi Tabuchi: Department of Chemistry and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, Japan
Seiki Tomohara: Department of Chemistry and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, Japan
Motohiro Tsuboi: Department of Chemistry and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, Japan
Daisuke Yoshioka: Department of Chemistry and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, Japan
Hiroshi Sakiyama: Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, 1-4-12 Kojirakawa, Yamagata 990-8560, Japan
Akira Fuyuhiro: Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan

Journal volume & issue: Vol. 9, no. 1
pp. 100 – 105

Abstract

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Mixed-valent tetranuclear MnIIMnIII3 complex with 1,3-dimino-2-hydroxypropane-N,N’-N”-N”’-tetracetic acid, Ca2[Mn4{µ-OHO}(dhpta)2(CH3COO)2], where considerable antiferromagnetic interactions are operating, was synthesized and characterized by elemental analysis and IR and UV-vis spectroscopies, temperature dependence of magnetic susceptibilities (4.5—300K), and single-crystal X-ray crystallography.

Published in Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry

ISSN: 1857-1727 (Print); 2345-1688 (Online)
Publisher: Academy of Sciences of Moldova, Institute of Chemistry
Country of publisher: Moldova, Republic of
LCC subjects: Science: Chemistry: General. Including alchemy
Website: http://www.cjm.asm.md/

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