Acta Crystallographica Section E (Apr 2012)

Diaquabis(pyrazine-2-carboxamide-κ2N1,O)cobalt(II) dinitrate

  • Ajay Pal Singh Pannu,
  • Seona Lee,
  • Yongjae Lee

DOI
https://doi.org/10.1107/S1600536812012573
Journal volume & issue
Vol. 68, no. 4
pp. m512 – m513

Abstract

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The asymmetric unit of the title complex, [Co(C5H5N3O)2(H2O)2](NO3)2, contains one half of a CoII cationic unit and a nitrate anion. The entire [Co(C5H5N3O)2(H2O)2]2+ cationic unit is completed by the application of inversion symmetry at the CoII site, generating a six-coordinate distorted octahedral environment for the metal ion. The chelating pyrazine-2-carboxamide molecules are bound to cobalt via N and O atoms, forming a square plane, while the remaining two trans positions in the octahedron are occupied by two coordinated water molecules.