Effects of Coordination Ability of Nitrogen-Containing Carboxylic Acid Ligands on Nieuwland Catalyst

Abstract

This article investigated the effect of three nitrogen-containing carboxylic acid ligands for the Nieuwland catalyst system. The catalyst system containing 4.5% N-(2-acetamido) iminodiacetic acid exhibited improved catalytic activity with excellent performance. The yield of monovinylacetylene (MVA) was maintained at 36.7% after 24 h, which was increased by 17.1% relative to the Nieuwland catalyst system. Based on a variety of analyses on the crystals precipitated from the catalyst solutions, it can be inferred that the outstanding performance and lifetime of the catalysts were related to the abilities of these ligands to form strong coordination with Cu+ ions and stabilize them.

Keywords

• Nieuwland catalyst
• acetylene dimerization
• monovinylacetylene
• nitrogen-containing carboxylic acid ligands