Dual Properties of Polyvinyl Alcohol-Based Magnetorheological Plastomer with Different Ratio of DMSO/Water
Norhiwani Mohd Hapipi,
Saiful Amri Mazlan,
Ubaidillah Ubaidillah,
Siti Aishah Abdul Aziz,
Seung-Bok Choi,
Nur Azmah Nordin,
Nurhazimah Nazmi,
Zhengbin Pang,
Shahir Mohd Yusuf
Affiliations
Norhiwani Mohd Hapipi
Engineering Materials and Structures (eMast) iKohza, Malaysian-Japan International Institute of Technology, Universiti Teknologi Malaysia, Jalan Sultan Yahya Petra, Kuala Lumpur 54100, Malaysia
Saiful Amri Mazlan
Engineering Materials and Structures (eMast) iKohza, Malaysian-Japan International Institute of Technology, Universiti Teknologi Malaysia, Jalan Sultan Yahya Petra, Kuala Lumpur 54100, Malaysia
Ubaidillah Ubaidillah
Mechanical Engineering Department, Faculty of Engineering, Universitas Sebelas Maret, Jl. Ir. Sutami 36A Kentingan Jebres, Surakarta 57126, Indonesia
Siti Aishah Abdul Aziz
Engineering Materials and Structures (eMast) iKohza, Malaysian-Japan International Institute of Technology, Universiti Teknologi Malaysia, Jalan Sultan Yahya Petra, Kuala Lumpur 54100, Malaysia
Seung-Bok Choi
Department of Mechanical Engineering, The State University of New York, Korea (SUNY Korea), 119 Songdo Moonhwa-Ro, Yeonsu-Gu, Incheon 21985, Korea
Nur Azmah Nordin
Engineering Materials and Structures (eMast) iKohza, Malaysian-Japan International Institute of Technology, Universiti Teknologi Malaysia, Jalan Sultan Yahya Petra, Kuala Lumpur 54100, Malaysia
Nurhazimah Nazmi
Engineering Materials and Structures (eMast) iKohza, Malaysian-Japan International Institute of Technology, Universiti Teknologi Malaysia, Jalan Sultan Yahya Petra, Kuala Lumpur 54100, Malaysia
Zhengbin Pang
Engineering Materials and Structures (eMast) iKohza, Malaysian-Japan International Institute of Technology, Universiti Teknologi Malaysia, Jalan Sultan Yahya Petra, Kuala Lumpur 54100, Malaysia
Shahir Mohd Yusuf
Engineering Materials and Structures (eMast) iKohza, Malaysian-Japan International Institute of Technology, Universiti Teknologi Malaysia, Jalan Sultan Yahya Petra, Kuala Lumpur 54100, Malaysia
Polyvinyl alcohol (PVA)-based magnetorheological plastomer (MRP) possesses excellent magnetically dependent mechanical properties such as the magnetorheological effect (MR effect) when exposed to an external magnetic field. PVA-based MRP also shows a shear stiffening (ST) effect, which is very beneficial in fabricating pressure sensor. Thus, it can automatically respond to external stimuli such as shear force without the magnetic field. The dual properties of PVA-based MRP mainly on the ST and MR effect are rarely reported. Therefore, this work empirically investigates the dual properties of this smart material under the influence of different solvent compositions (20:80, 40:60, 60:40, and 80:20) by varying the ratios of binary solvent mixture (dimethyl sulfoxide (DMSO) to water). Upon applying a shear stress with excitation frequencies from 0.01 to 10 Hz, the storage modulus (G′) for PVA-based MRP with DMSO to water ratio of 20:40 increases from 6.62 × 10−5 to 0.035 MPa. This result demonstrates an excellent ST effect with the relative shear stiffening effect (RSTE) up to 52,827%. In addition, both the ST and MR effect show a downward trend with increasing DMSO content to water. Notably, the physical state of hydrogel MRP could be changed with different solvent ratios either in the liquid-like or solid-like state. On the other hand, a transient stepwise experiment showed that the solvent’s composition had a positive effect on the arrangement of CIPs within the matrix as a function of the external magnetic field. Therefore, the solvent ratio (DMSO/water) can influence both ST and MR effects of hydrogel MRP, which need to be emphasized in the fabrication of hydrogel MRP for appropriate applications primarily with soft sensors and actuators for dynamic motion control.
