Advanced Electronic Materials (Jul 2024)

Dry Laser‐Induced Graphene Fractal‐like ECG Electrodes

  • Yann Houeix,
  • Denice Gerardo,
  • Francisco J. Romero,
  • Víctor Toral,
  • Lidia Hernandez,
  • Almudena Rivadeneyra,
  • Encarnación Castillo,
  • Diego P. Morales,
  • Noel Rodriguez

DOI
https://doi.org/10.1002/aelm.202300767
Journal volume & issue
Vol. 10, no. 7
pp. n/a – n/a

Abstract

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Abstract Fractal‐like geometries applied to biosignal‐electrodes design show great potential for enhancing the signal acquisition of sensing systems. This study reports a novel approach for flexible, silver‐free, and dry fractal‐like electrodes based on Laser‐Induced Graphene (LIG) obtained through laser photothermal processing of a commercial polyimide film. This one‐step mask‐less manufacturing process enables the simple fabrication of natural and optimized fractal‐like shapes inspired by actual snowflake patterns. To ensure a reliable and standardized connection to the measurement unit, the electrodes are equipped with a snap terminal. The electrodes are structurally characterized using various techniques including Scanning Electron Microscopy (SEM), Raman spectroscopy, and X‐ray Photoelectron Spectroscopy (XPS). By benchmarking the performance of these electrodes against Ag/AgCl wet commercial electrodes and LIG electrodes shaped as commercial ones, a heart rate‐monitoring accuracy of over 96.8% is achieved, with high specificity, positive prediction, and sensitivity, surpassing the 95.8% achieved by conventional commercial electrodes. These results demonstrate the efficacy of fractal‐based designs in combination with LIG‐based transduction, offering flexible and cost‐effective electrocardiogram (ECG) electrodes with improved performance compared to traditional wet electrodes.

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