Micromachines (Jan 2023)

Achieving Self-Supported Hierarchical Cu(OH)<sub>2</sub>/Nickel–Cobalt Sulfide Electrode for Electrochemical Energy Storage

  • Sa Lv,
  • Wenshi Shang,
  • Yaodan Chi,
  • Huan Wang,
  • Xuefeng Chu,
  • Boqi Wu,
  • Peiyu Geng,
  • Chao Wang,
  • Jia Yang,
  • Zhifei Cheng,
  • Xiaotian Yang

DOI
https://doi.org/10.3390/mi14010125
Journal volume & issue
Vol. 14, no. 1
p. 125

Abstract

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Herein, nickel–cobalt sulfide (NCS) nanoflakes covering the surface of Cu(OH)2 nanorods were achieved by a facile two-step electrodeposition strategy. The effect of CH4N2S concentration on formation mechanism and electrochemical behavior is investigated and optimized. Thanks to the synergistic effect of the selected composite components, the Cu(OH)2/NCS composite electrode can deliver a high areal specific capacitance (Cs) of 7.80 F cm−2 at 2 mA cm−2 and sustain 5.74 F cm−2 at 40 mA cm−2. In addition, coulombic efficiency was up to 84.30% and cyclic stability remained 82.93% within 5000 cycles at 40 mA cm−2. This innovative work provides an effective strategy for the design and construction of hierarchical composite electrodes for the development of energy storage devices.

Keywords