Acta Crystallographica Section E (Aug 2009)

Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)nickel(II) ethane-1,2-diol solvate

  • Jian-Mei Wang,
  • Chao Ni,
  • Kai-Long Zhong

DOI
https://doi.org/10.1107/S1600536809026269
Journal volume & issue
Vol. 65, no. 8
pp. m911 – m911

Abstract

Read online

In the title compound, [Ni(SO4)(C12H8N2)2]·C2H6O2, the coordination polyhedron around the Ni2+ ion is a distorted octahedron, with four N atoms from two phenanthroline groups and two O atoms from a bidentate sulfate ligand. The Ni2+ ion lies on a special position of site symmetry 2. Intermolecular O—H...O hydrogen bonds help to stabilize the structure. The OH group of the ethane-1,2-diol solvent is disordered over two positions with equal occupancy.