Acta Crystallographica Section E (Jun 2013)

Aquatrimethyl[2-(4-methylpyrimidin-2-ylsulfanyl)acetato-κO]tin(IV)

  • Zhiqing Gao,
  • Junhong Zhang,
  • Xuyi Hao,
  • Daqi Wang,
  • Tingting Zhang

DOI
https://doi.org/10.1107/S1600536813012622
Journal volume & issue
Vol. 69, no. 6
pp. m313 – m313

Abstract

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In the title compound, [Sn(CH3)3(C7H7N2O2S)(H2O)], the SnIV atom has a distorted trigonal–bipyramidal coordination geometry, with one carboxylate O atom of the 2-(4-methylpyrimidine-2-sulfanyl)acetate ligand and the O atom of a water molecule in axial positions, and three methyl groups in equatorial positions. In the crystal, molecules are linked via O—H...O and O—H...N hydrogen bonds, forming double-stranded chains propagating along [010].