Acta Crystallographica Section E (Oct 2009)

Bis[4-oxido-2-oxo-2,3-dihydropyrimidin-1-ium-5-carboxylato(1.5−)-κ2O4,O5]bis(1,10-phenanthroline-κ2N,N′)dysprosium(III) dihydrate

  • Xianlin Liu,
  • Huihui Xing,
  • Jing Miao,
  • Maomao Jia,
  • Zilu Chen

DOI
https://doi.org/10.1107/S1600536809036848
Journal volume & issue
Vol. 65, no. 10
pp. m1224 – m1225

Abstract

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In the title compound, [Dy(C5H2.5N2O4)2(C12H8N2)2]·2H2O, the DyIII ion is located on a twofold rotation axis and is coordinated in a square-antiprismatic geometry by two chelating 1,10-phenanthroline molecules as well as two 4-oxido-2-oxo-2,3-dihydropyrimidin-1-ium-5-carboxylato(1.5−) anions. N—H...O and O—H...O hydrogen bonds help to stabilize the crystal structure. The H atom involved in an N—H...N hydrogen bond is disordered around a twofold rotation axis.