Hydride-based antiperovskites with soft anionic sublattices as fast alkali ionic conductors

Shenghan Gao; Thibault Broux; Susumu Fujii; Cédric Tassel; Kentaro Yamamoto; Yao Xiao; Itaru Oikawa; Hitoshi Takamura; Hiroki Ubukata; Yuki Watanabe; Kotaro Fujii; Masatomo Yashima; Akihide Kuwabara; Yoshiharu Uchimoto; Hiroshi Kageyama

doi:10.1038/s41467-020-20370-2

Nature Communications (Jan 2021)

Hydride-based antiperovskites with soft anionic sublattices as fast alkali ionic conductors

Shenghan Gao,
Thibault Broux,
Susumu Fujii,
Cédric Tassel,
Kentaro Yamamoto,
Yao Xiao,
Itaru Oikawa,
Hitoshi Takamura,
Hiroki Ubukata,
Yuki Watanabe,
Kotaro Fujii,
Masatomo Yashima,
Akihide Kuwabara,
Yoshiharu Uchimoto,
Hiroshi Kageyama

Affiliations

Shenghan Gao: Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University
Thibault Broux: Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University
Susumu Fujii: Nanostructures Research Laboratory, Japan Fine Ceramics Center
Cédric Tassel: Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University
Kentaro Yamamoto: Graduate School of Human and Environmental Studies, Kyoto University
Yao Xiao: Graduate School of Human and Environmental Studies, Kyoto University
Itaru Oikawa: Department of Materials Science, Graduate School of Engineering, Tohoku University
Hitoshi Takamura: Department of Materials Science, Graduate School of Engineering, Tohoku University
Hiroki Ubukata: Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University
Yuki Watanabe: Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University
Kotaro Fujii: Department of Chemistry, School of Science, Tokyo Institute of Technology
Masatomo Yashima: Department of Chemistry, School of Science, Tokyo Institute of Technology
Akihide Kuwabara: Nanostructures Research Laboratory, Japan Fine Ceramics Center
Yoshiharu Uchimoto: Graduate School of Human and Environmental Studies, Kyoto University
Hiroshi Kageyama: Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University

DOI: https://doi.org/10.1038/s41467-020-20370-2
Journal volume & issue: Vol. 12, no. 1
pp. 1 – 10

Abstract

Read online

Oxide-based lithium/sodium-rich antiperovskites are regarded as promising solid electrolytes. Here, authors report a series of antiperovskites with a soft lattice containing hydride (H–) and chalcogenide (S2–, Se2–, Te2–) anions, enabling the fast Li+ /Na+ transport assisted by rotational phonon modes.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

About the journal