IUCrData (Nov 2022)

Bis(4′-chloro-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)zinc(II) bis(trifluoromethanesulfonate)

  • Rafael A. Adrian,
  • Sara J. Ibarra,
  • Hadi D. Arman

DOI
https://doi.org/10.1107/S2414314622010963
Journal volume & issue
Vol. 7, no. 11
p. x221096

Abstract

Read online

In the title complex, [Zn(C15H10ClN3)2](CF3SO3)2, the ZnII metal center is sixfold coordinated by three nitrogen atoms of each 4-chloroterpyridine ligand in a distorted octahedral geometry with triflouromethanesulfonate ions completing the outer coordination sphere of the complex. π–π stacking interactions between the pyridyl rings in adjacent molecules contribute to the alignment of the complexes in layers along the c axis.

Keywords