Molecules
(May 2018)
Enantiomerically Enriched 1,2-P,N-Bidentate Ferrocenyl Ligands for 1,3-Dipolar Cycloaddition and Transfer Hydrogenation Reactions
Irina A. Utepova,
Polina O. Serebrennikova,
Marina S. Streltsova,
Alexandra A. Musikhina,
Tatiana G. Fedorchenko,
Oleg N. Chupakhin,
Andrey P. Antonchick
Affiliations
Irina A. Utepova
Ural Federal University, 19 Mira Street, Ekaterinburg 620002, Russia
Polina O. Serebrennikova
Ural Federal University, 19 Mira Street, Ekaterinburg 620002, Russia
Marina S. Streltsova
Ural Federal University, 19 Mira Street, Ekaterinburg 620002, Russia
Alexandra A. Musikhina
Ural Federal University, 19 Mira Street, Ekaterinburg 620002, Russia
Tatiana G. Fedorchenko
Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22 S. Kovalevskaya Street, Ekaterinburg 620041, Russia
Oleg N. Chupakhin
Ural Federal University, 19 Mira Street, Ekaterinburg 620002, Russia
Andrey P. Antonchick
Chemische Biologie, Max-Planck-Institut für Molekulare Physiologie, Otto-Hahn Strasse 11, 44227 Dortmund, Germany
DOI
https://doi.org/10.3390/molecules23061311
Journal volume & issue
Vol. 23,
no. 6
Abstract
Read online
Novel complexes of 1,2-P,N-bidentate ferrocenyl ligands with AgOAc or with [RuCl2(PPh3)3] as catalysts have been studied in asymmetric synthesis. The catalytic activity of these systems have been studied in [3+2]-cycloaddition of azomethine ylides with olefins and the asymmetric transfer hydrogenation of ketones.
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