IUCrData (Apr 2016)

4-Bromo-N-(4-bromophenyl)benzenesulfonamide

  • Vinola Z. Rodrigues,
  • S. Naveen,
  • N. K. Lokanath,
  • P. A. Suchetan

DOI
https://doi.org/10.1107/S2414314616006313
Journal volume & issue
Vol. 1, no. 4
p. x160631

Abstract

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The molecule of the title compound, C12H9Br2NO2S, is U shaped with the central C—S—N—C segment having a torsion angle of 63.2 (4)°. Further, the dihedral angle between the benzene rings is 38.5 (2)°. The crystal structure features strong N—H...O hydrogen bonds that form infinite [100] C(4) chains. Molecules in adjacent chains are interlinked via C—H...O interactions which run along the b axis, forming C(7) chains. This results in a two-dimensional network in the ab plane; adjacent networks are connected by short Br...Br contacts [3.5092 (8) Å] propagating along the diagonal of the ac plane, so that a three-dimensional supramolecular architecture ensues.

Keywords