Manipulation of the through‐space interactions in diphenylmethane

Weihao Tu; Zuping Xiong; Ziteng Zhang; Jianyu Zhang; Lei Wang; Yuan Xie; Yipu Wang; Haoke Zhang; Jing Zhi Sun; Ben Zhong Tang

doi:10.1002/smo.20220006

Smart Molecules (Sep 2023)

Manipulation of the through‐space interactions in diphenylmethane

Weihao Tu,
Zuping Xiong,
Ziteng Zhang,
Jianyu Zhang,
Lei Wang,
Yuan Xie,
Yipu Wang,
Haoke Zhang,
Jing Zhi Sun,
Ben Zhong Tang

Affiliations

Weihao Tu: MOE Key Laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and Engineering Zhejiang University Hangzhou China
Zuping Xiong: MOE Key Laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and Engineering Zhejiang University Hangzhou China
Ziteng Zhang: MOE Key Laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and Engineering Zhejiang University Hangzhou China
Jianyu Zhang: Department of Chemistry Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction The Hong Kong University of Science and Technology Hong Kong China
Lei Wang: MOE Key Laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and Engineering Zhejiang University Hangzhou China
Yuan Xie: ZJU‐Hangzhou Global Scientific and Technological Innovation Center Hangzhou China
Yipu Wang: MOE Key Laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and Engineering Zhejiang University Hangzhou China
Haoke Zhang: MOE Key Laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and Engineering Zhejiang University Hangzhou China
Jing Zhi Sun: MOE Key Laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and Engineering Zhejiang University Hangzhou China
Ben Zhong Tang: MOE Key Laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and Engineering Zhejiang University Hangzhou China

DOI: https://doi.org/10.1002/smo.20220006
Journal volume & issue: Vol. 1, no. 2
pp. n/a – n/a

Abstract

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Abstract Through‐space interaction (TSI) has been proven to play an important role in the newly emerging clusteroluminescence (CL) phenomenon. However, it is still a big challenge to manipulate the TSI at the molecular level due to the unclear relationship between the non‐conjugated structure and TSI properties. Herein, the TSI in diphenylmethane is manipulated by breaking its symmetric structures and changing the isolated subunits. Finally, the CL wavelength and efficiency of diphenylmethane are successfully regulated at the aggregate state.

Published in Smart Molecules

ISSN: 2751-4587 (Print); 2751-4595 (Online)
Publisher: Wiley
Country of publisher: Australia
LCC subjects: Science: Chemistry
Website: https://onlinelibrary.wiley.com/journal/27514595

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