Modeling and Simulation of Single Flow Zinc–Nickel Redox Battery Coupled with Multi-Physics Fields

Abstract

Metallic zinc (Zn) presents a compelling alternative to conventional electrochemical energy storage systems due to its environmentally friendly nature, abundant availability, high water compatibility, low toxicity, low electrochemical potential (−0.762 V vs. SHE), and cost-effectiveness. While considerable efforts have been devoted to enhancing the physical and chemical properties of zinc-ion battery materials to improve battery efficiency and longevity, research on multi-physics coupled modeling for a deeper understanding of battery performance remains relatively scarce. In this study, we established a comprehensive two-dimensional model for single-flow zinc–nickel redox batteries to investigate electrode reactions, current-potential behaviors, and concentration distributions, leveraging theories such as Nernst–Planck and Butler–Volmer. Additionally, we explored the distribution of the velocity field using the Brinkman theory in porous media and the Navier–Stokes equations in free-flow channels. The validated model, informed by experimental data, not only provides insights into the performance of the battery, but also offers valuable recommendations for advancing single-flow zinc–nickel battery technology. Our findings offer promising avenues for enhancing the design and performance of not only zinc–nickel flow batteries, but also applicable for other flow battery designs.

Keywords

• single-flow zinc–nickel redox battery
• redox flow battery
• numerical simulation
• finite element analysis
• concentration distribution
• current-potential behavior