Nature Communications (Jan 2023)
Understanding the failure process of sulfide-based all-solid-state lithium batteries via operando nuclear magnetic resonance spectroscopy
- Ziteng Liang,
- Yuxuan Xiang,
- Kangjun Wang,
- Jianping Zhu,
- Yanting Jin,
- Hongchun Wang,
- Bizhu Zheng,
- Zirong Chen,
- Mingming Tao,
- Xiangsi Liu,
- Yuqi Wu,
- Riqiang Fu,
- Chunsheng Wang,
- Martin Winter,
- Yong Yang
Affiliations
- Ziteng Liang
- State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University
- Yuxuan Xiang
- State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University
- Kangjun Wang
- State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University
- Jianping Zhu
- State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University
- Yanting Jin
- State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University
- Hongchun Wang
- College of Energy, Xiamen University
- Bizhu Zheng
- State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University
- Zirong Chen
- State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University
- Mingming Tao
- State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University
- Xiangsi Liu
- State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University
- Yuqi Wu
- College of Energy, Xiamen University
- Riqiang Fu
- National High Magnetic Field Laboratory
- Chunsheng Wang
- Department of Chemical and Biomolecular Engineering, University of Maryland
- Martin Winter
- MEET Battery Research Center, Institute of Physical Chemistry, University of Münster
- Yong Yang
- State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University
- DOI
- https://doi.org/10.1038/s41467-023-35920-7
- Journal volume & issue
-
Vol. 14,
no. 1
pp. 1 – 15
Abstract
All-solid-state lithium batteries performance is affected by the solid electrolyte interphase (SEI) and electrically disconnected (“dead”) Li metal. Here, via operando NMR measurements, the authors quantify the Li metal in the SEI and “dead” regions using various inorganic solid-state electrolytes.
