Preparation and Physicochemical Properties of Tannin-Immobilized Membrane Adsorbent

Abstract

Plant tannins have the ability to form stable complexes with metal ions, while microporous membranes have low pressure drop and high flux characteristics. Combining these two materials, a new type of tannin-immobilized membrane (M-TAN) adsorption material has been developed. The PA-BWT, PVDF-BWT, CELL -BWT, and PA-AA-BWT were prepared using different types of microporous membranes as substrates, which maintained the porous structure of the membranes and had the characteristics of high flux and fast filtration rate. The surface contact angle and pure water flux analysis showed that the introduction of tannin with multi-phenolic hydroxyl groups increased the hydrophilicity and water flux of the M-TANs. The adsorption performance shows that the adsorption capacity of four kinds of M-TANs for UO22+ is in the order of PA-BWT > PA-AA-BWT > PVDF-BWT > CELL-BWT, and PA-BWT has the largest adsorption capacity of 0.398 mmol g−1. In addition, the adsorption isothermal and kinetic data of PA-BWT were well fitted by the Langmuir equation and the Elovich model, respectively. The negative values of ΔG for UO22+ adsorption on PA-BWT indicated that adsorption is a spontaneous and favorable process. These facts indicate that PA-BWT can be used as a low-cost adsorbent for effective removal of UO22+ from aqueous solutions.

Keywords

• plant tannins
• microporous membranes
• immobilized tannins
• membrane adsorption