Acta Crystallographica Section E (Jun 2011)

Bis(1,3-dimesitylimidazolyl)gold(I) 2,4,8,10-tetraphenyl-1,3,5,7,9,11-hexaoxa-2,4,8,10-tetrabora-6-borataspiro[5.5]undecane

  • Lennart Möhlmann,
  • Ola F. Wendt,
  • Magnus T. Johnson

DOI
https://doi.org/10.1107/S1600536811016357
Journal volume & issue
Vol. 67, no. 6
pp. m719 – m720

Abstract

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The AuI atom in the title compound, [Au(C21H24N2)2](C24H20B5O6), adopts a slightly distorted linear AuC2 coordination geometry arising from its coordination by two mesitylenic N-heterocyclic carbene ligands, forming an overall cationic complex. The dihedral angle between the imidazole rings is 57.3 (6)°. In the crystal, the components are linked by weak C—H...O hydrogen bonds.