Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ (Nov 2016)

SOME QUESTIONS OF THE SPECIATION ANALYSIS

  • V. P. Antonovich,
  • I. V. Stoyanova,
  • N. A. Chivireva,
  • A. O. Stoyanov

DOI
https://doi.org/10.18524/2304-0947.2016.4(60).83661
Journal volume & issue
Vol. 21, no. 4(60)
pp. 6 – 20

Abstract

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Speciation analysis is considered to be one of actual trends of modern analytical chemistry. Based on the numerous monographs and reviews its general principles and features are reviewed. It was noticed that increasing of the interest in the speciation analysis in the last years is connected with mainly biomedical and ecological tasks. Conclusion about insufficient attention to the problems of determination of chemical forms of the components of different inorganic functional materials is drawn. Such tasks require maintenance of initials forms of the analyte during transferring sample into the solution. Combination of procedure of dissolution of the sample in presence of reagents that selectively and quantitatively react with the determined chemical form of element is confessed to be optimal. As well as nondestructive methods of forms detection. For this purpose, spectroscopy of diffuse reflection can be recommended.

Keywords