Influence of ultrasonication time on the various properties of alkaline-treated mango seed waste filler reinforced PVA biocomposite

Abstract

The usage of biodegradable materials is gaining mounting applications owing to the environmental problems created by petroleum-based synthetic materials. Agro-waste materials are finding more scope as reinforcement materials in polymer composites, mainly because of their cost-effectiveness and availability. The main aim of this research work is to utilize agro-waste material in the form of mango seed waste (MSW) as a reinforcing material with polyvinyl alcohol (PVA) to form biocomposite. The biocomposites were fabricated using the solution casting technique. The research work focuses on the influence of varying ultrasonication periods (0–20 min at 5-min intervals, i.e., 0, 5, 10, 15, and 20 min) on the properties of PVA/MSW biocomposites. The fabricated biocomposites were subjected to tensile test, fracture morphology, moisture absorption (MA), Fourier transform infrared spectroscopy, and thermogravimetric analysis. The results revealed that the material with the highest tensile strength was 3.95 MPa obtained with the 20-min ultrasonication sample. This value is 49% higher than that obtained in the sample without ultrasonication. The scanning electron microscopy analysis shows that the 20-min ultrasonication sample indicated a good distribution of MSW fillers in the PVA contrasted with the rest of the samples. The thermal stability of the samples treated with ultrasonication was found to be significantly higher than that of the untreated samples, whereas the MA value decreased with increasing ultrasonication time. It can be observed from the results that biocomposites can be a potential alternative to the synthetic materials used in packaging applications.

Keywords

• biocomposite
• polyvinyl alcohol
• mango seed waste filler
• ultrasonication effect
• mechanical properties
• thermal stability