Magnetic Property, Heat Capacity and Crystal Structure of Mononuclear Compounds Based on Substitute Tetrazole Ligand
Hui Zheng,
Jipeng Luo,
Xiaoqin Wang,
Nan Yin,
Beibei Zhang,
Xuezhen Gao,
Zongzheng Zhang,
Quan Shi,
Junshen Liu
Affiliations
Hui Zheng
School of Chemistry and Materials Science, Ludong University, Yantai 264025, China
Jipeng Luo
Thermochemistry Laboratory, Dalian Technology Innovation Center for Energy Materials Thermodynamics, Liaoning Province Key Laboratory of Thermochemistry for Energy and Materials, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
Xiaoqin Wang
School of Chemistry and Materials Science, Ludong University, Yantai 264025, China
Nan Yin
Thermochemistry Laboratory, Dalian Technology Innovation Center for Energy Materials Thermodynamics, Liaoning Province Key Laboratory of Thermochemistry for Energy and Materials, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
Beibei Zhang
School of Chemistry and Materials Science, Ludong University, Yantai 264025, China
Xuezhen Gao
School of Chemistry and Materials Science, Ludong University, Yantai 264025, China
Zongzheng Zhang
School of Chemistry and Materials Science, Ludong University, Yantai 264025, China
Quan Shi
Thermochemistry Laboratory, Dalian Technology Innovation Center for Energy Materials Thermodynamics, Liaoning Province Key Laboratory of Thermochemistry for Energy and Materials, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
Junshen Liu
School of Chemistry and Materials Science, Ludong University, Yantai 264025, China
Three mononuclear compounds formulated as {M[(2-1H-tetrazol-5-yl)pyridine]2(H2O)2} (M = FeII (1), CoII (2), CuII (3)) were reported and synthesized. Their space group is monoclinic, P21/c, revealed by single-crystal X-ray diffraction. Antiferromagnetic interactions exist in Compounds 1, 2 and 3, as evidenced by magnetic and low-temperature heat capacity measurements. In addition, their thermodynamic functions were determined by a relaxation calorimeter, indicating that Compound 1 exhibits a Schottky anomaly in low-temperature heat capacity. This work can provide an important fundamental basis for the research of the thermophysical properties of molecular-based magnetic materials.
