Adsorption Characteristics of Phenolic Compounds on Graphene Oxide and Reduced Graphene Oxide: A Batch Experiment Combined Theory Calculation

Abstract

A series of phenolic compounds containing 2-phenylphenol (PPE), bisphenol A (BPA), 4-isopropylphenol (IPE), 4-methylphenol (ME) and phenol (PE) were selected to investigate their major influence factors for their adsorption on graphene oxide (GO) and reduced graphene oxide (RGO) by studying their adsorption isotherms and kinetics. It was found that the adsorption of all tested phenols fitted well with the Freundlich model. In comparison, the adsorption ability of RGO with a stronger π-π interaction was superior to GO, which was confirmed by using naphthalene probe measurements. The thermodynamic characteristics, by studying the effect of the adsorption temperatures (298, 313 and 333 K), demonstrated that the adsorption process was spontaneous, exothermic and entropy-decreasing. The chemical structures of the phenols also affected their adsorption on GO and RGO. It was found that the adsorption capacities of phenols were, in order, PE (0.271 mmol g−1 on GO and 0.483 mmol g−1 on RGO) < ME (0.356 and 0.841 mmol g−1) < IPE (0.454 and 1.117 mmol g−1) < BPA (0.4 and 1.56 mmol g−1) < PPE (0.7 and 2.054 mmol g−1), which depended on the π-electron density of the benzene ring by means of a density functional theory (DFT) calculation. Undoubtedly, the reduction of GO and an increase in π-electron density on the chemical structures of phenols facilitated the adsorption.

Keywords

• reduced graphene oxide
• π-π interaction
• phenolic compounds
• adsorption