发电技术 (Apr 2023)

Long Period Operation of Ionic Liquid Based Electrical Double Layer Capacitor at 45 ℃ and 3 V

  • YE Zhenzhen,
  • CHEN Xinqi,
  • ZHANG Shuting,
  • WANG Jian,
  • CUI Chaojie,
  • ZHANG Gang,
  • ZHANG Lei,
  • QIAN Luming,
  • JIN Ying,
  • QIAN Weizhong

DOI
https://doi.org/10.12096/j.2096-4528.pgt.22116
Journal volume & issue
Vol. 44, no. 2
pp. 213 – 220

Abstract

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The long period operation at 45 ℃ and 3 V of the mesoporous carbon-ionic liquid-carbon covered aluminum foam based electrical double layer capacitor was studied. The composite electrode sheet was formed by embedding mesoporous carbon with carbon-coated aluminum foam, and the 3 cm×5 cm pouch was composed of EMIBF4 as electrolyte. The operation law of charge and discharge was studied at 45 ℃ and 3 V for 1 500 h. It is found that the internal resistance change rate is about 10%, and the capacitance retention rate is as high as 98%, both of which are far better than those of organic liquid-based electrical double layer capacitor at 2.7 V and 65 ℃. The gas generation of pouches at 2.7 V/65 ℃ and 3 V/45 ℃ was compared. It is proved that the soft package of mesoporous carbon-ionic liquid-carbon-coated aluminum foam based electrical double layer capacitor can work stably at 3 V, 45 ℃ for 1 500 h. It provides a solid foundation for further promoting the application of ionic liquid-based electrical double layer capacitor.

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