Acta Crystallographica Section E (Aug 2012)

(N-Benzoyl-N′,N′-diphenylthioureato-κ2S,O)(η4-cycloocta-1,5-diene)rhodium(I)

  • Stefan Warsink,
  • Andreas Roodt

DOI
https://doi.org/10.1107/S1600536812029753
Journal volume & issue
Vol. 68, no. 8
pp. m1053 – m1054

Abstract

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The title complex, [Rh(C20H15N2OS)(C8H12)], exhibits an essentially square-planar coordination environment around the RhI atom, which bears a bidentate cyclooctadiene ligand as well as a monoanionic bidentate benzoylthioureate ligand. The RhI atom, the S- and O-donor atoms and the alkene centroids of the cyclooctadiene ligand do not deviate by more than 0.031 Å from their least mean-squares plane.