Acta Crystallographica Section E (Aug 2012)
(N-Benzoyl-N′,N′-diphenylthioureato-κ2S,O)(η4-cycloocta-1,5-diene)rhodium(I)
Abstract
The title complex, [Rh(C20H15N2OS)(C8H12)], exhibits an essentially square-planar coordination environment around the RhI atom, which bears a bidentate cyclooctadiene ligand as well as a monoanionic bidentate benzoylthioureate ligand. The RhI atom, the S- and O-donor atoms and the alkene centroids of the cyclooctadiene ligand do not deviate by more than 0.031 Å from their least mean-squares plane.