Química Nova (Jan 2013)

Estudio hidrofóbico de soluciones acuosas diluidas de isómeros de pentanodiol a varias temperaturas a partir de datos volumétricos

  • Alfonso A. Portacio,
  • Manuel S. Páez,
  • María del Pilar Urango

DOI
https://doi.org/10.1590/S0100-40422013000900019
Journal volume & issue
Vol. 36, no. 9
pp. 1388 – 1390

Abstract

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Density of dilute aqueous solutions of 1,2 pentanediol, 2,4 pentanediol, 1,4 pentanediol and 1,5 pentanediol at 283.15, 288.15, 293.15, 298.15, 303.15 and 308.15 K in the concentration range 0.0000 to 0.0060 in mole fraction were determined by using Wood-Brusie type capillary neck pycnometers. The solute partial molar volume as a function of solute concentration for each system was correlated with a linear equation for each temperature to estimate the slope limit and the partial molar volume at infinite dilution, and the predominant hydrophilic-hydrophobic effect was found in this region.

Keywords