Synthesis of cross-conjugated trienes by rhodium-catalyzed dimerization of monosubstituted allenes

Tomoya Miura; Tsuneaki Biyajima; Takeharu Toyoshima; Masahiro Murakami

doi:10.3762/bjoc.7.67

Beilstein Journal of Organic Chemistry (May 2011)

Synthesis of cross-conjugated trienes by rhodium-catalyzed dimerization of monosubstituted allenes

Tomoya Miura,
Tsuneaki Biyajima,
Takeharu Toyoshima,
Masahiro Murakami

Affiliations

Tomoya Miura: Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto 615-8510, Japan
Tsuneaki Biyajima: Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto 615-8510, Japan
Takeharu Toyoshima: Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto 615-8510, Japan
Masahiro Murakami: Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto 615-8510, Japan

DOI: https://doi.org/10.3762/bjoc.7.67
Journal volume & issue: Vol. 7, no. 1
pp. 578 – 581

Abstract

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A rhodium(I)/dppe catalyst promoted dimerization of monosubstituted allenes in a stereoselective manner to give cross-conjugated trienes, which are different from those obtained by a palladium catalyst.

Published in Beilstein Journal of Organic Chemistry

ISSN: 1860-5397 (Online)
Publisher: Beilstein-Institut
Country of publisher: Germany
LCC subjects: Science: Chemistry: Organic chemistry
Website: http://www.beilstein-journals.org/bjoc

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