Acta Crystallographica Section E (Aug 2010)

[(1R,4S)-(+)-3-Benzoyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-olato-κ2O2,O3](η4-norbornadiene)rhodium(I)

  • Mohamed Anoir Harrad,
  • Brahim Boualy,
  • Mustapha Ait Ali,
  • Larbi El Firdoussi,
  • Corrado Rizzoli

DOI
https://doi.org/10.1107/S160053681002667X
Journal volume & issue
Vol. 66, no. 8
pp. m915 – m916

Abstract

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In the title complex molecule, [Rh(C17H19O2)(C7H8)], the rhodium(I) metal centre is coordinated by the O atoms of a benzoylcamphorate anion and the C=C bonds of the norbornadiene molecule into a slightly distorted square-planar coordination geometry. The six-membered chelate ring is essentially planar (r.m.s. deviation = 0.0378 Å) and forms a dihedral angle of 31.67 (11)° with the phenyl ring.