Highly Sensitive p-SmFeO₃/p-YFeO₃ Planar-Electrode Sensor for Detection of Volatile Organic Compounds

Abstract

Nanocomposites of SmFeO3/YFeO3 (1:0, 0.8:0.2, 0.6:0.4, 0.4:0.6, 0.2:0.8, and 0:1) with different molar proportions were prepared by the sol–gel method. The material’s properties were characterized by various test methods, such as scanning-electron microscopy (SEM) and X-ray photoelectron-diffraction spectrometry (XPS). The gas-sensing characteristics of the sensor were tested in darkness and under illumination using monochromatic light with various selected wavelengths. The test results show that the SmFeO3/YFeO3 sensor with the molar ratio of 0.4:0.6 had the highest gas response to volatile organic compound (VOC) gases and that the optimum operating temperature was lower (120 °C). The light illumination improved the sensor’s sensitivity to gas. Under the 370-nanometer light illumination, the sensor’s responses to 30 ppm of ethanol, acetone, and methanol gases were 163.59, 134.02, and 111.637, respectively, which were 1.35, 1.28, and 1.59 times higher, respectively, than those without light. The high gas sensitivity of the sensor was mainly due to the adsorption of oxygen on the material’s surface and the formation of a p–p heterojunction. The SmFeO3/YFeO3 sensor, which can respond to different VOC gases, can be used to detect the safety of unknown environments and provide a timely warning of the presence of dangerous gases in working environments.

Keywords

• heterojunction
• gas sensor
• light illumination
• volatile organic compound
• sensing characteristics
• sensing mechanism