Eclética Química (Apr 2018)

EMISSÃO QUASE BRANCA DE UM COMPLEXO BINUCLEAR DE DISPRÓSIO(III) CONTENDO DICARBOXILATOS

  • Marcelo G. Lahoud,
  • Marian R. Davolos,
  • Caio A. S. de Jesus,
  • Regina C. G. Frem

DOI
https://doi.org/10.26850/1678-4618eqj.v38.1.2013.p95-100
Journal volume & issue
Vol. 38, no. 1
pp. 95 – 100

Abstract

Read online

This work reports the synthesis and characterization of the novel [Dy2(dcpz)2(suc)(H2O)8](H2O)1.5 (dcpz = 3,5-dicarboxypyrazolate, suc = succinate). The structure should probably consist of a binuclear species in which Dy3+ ions are linked by two different bridging organic ligands. Luminescent studies were carried out and revealed that the Dy3+complex exhibits a near white emission under UV excitation.