Acta Crystallographica Section E (Oct 2008)

1-(2′,4′-Difluorobiphenyl-4-yl)ethanone

  • Lin Yuan,
  • Hui-Rui Guo,
  • Qiao-Chu Zhang,
  • Ji-Hua Deng,
  • Meng-Ping Guo*

DOI
https://doi.org/10.1107/S1600536808028596
Journal volume & issue
Vol. 64, no. 10
pp. o1923 – o1923

Abstract

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In the crystal structure of the title compound, C14H10F2O, the dihedral angles between the benzene rings in the two crystallographically independent molecules are 46.9 (2) and 47.6 (2)°. The molecules are linked into dimers by C—H...F interactions and these dimers are further stacked into columns along the b axis by π–π interactions between the benzene rings [centroid–centroid distance = 3.8221 Å; the dihedral angle between the planes of these rings is 4.87 (2)°]. In addition, C—F...π interactions also contribute to the crystal packing (C...centroid distance = 3.5919 Å).