Catalytic and Stoichiometric <i>Baeyer–Villiger</i> Oxidation Mediated by Nonheme Peroxo-Diiron(III), Acylperoxo, and Iodosylbenzene Iron(III) Intermediates
Dóra Lakk-Bogáth,
Miklós István Szávuly,
Patrik Török,
József Kaizer
Affiliations
Dóra Lakk-Bogáth
Research Group of Bioorganic and Biocoordination Chemistry, Faculty of Engineering, Center for Natural Sciences, University of Pannonia, H-8201 Veszprém, Hungary
Miklós István Szávuly
Research Group of Bioorganic and Biocoordination Chemistry, Faculty of Engineering, Center for Natural Sciences, University of Pannonia, H-8201 Veszprém, Hungary
Patrik Török
Research Group of Bioorganic and Biocoordination Chemistry, Faculty of Engineering, Center for Natural Sciences, University of Pannonia, H-8201 Veszprém, Hungary
József Kaizer
Research Group of Bioorganic and Biocoordination Chemistry, Faculty of Engineering, Center for Natural Sciences, University of Pannonia, H-8201 Veszprém, Hungary
In this paper we describe a detailed mechanistic studies on the [FeII(PBO)2(CF3SO3)2] (1), [FeII(PBT)2(CF3SO3)2] (2), and [FeII(PBI)3](CF3SO3)2 (3)-catalyzed (PBO = 2-(2′-pyridyl)benzoxazole, PBT = 2-(2′-pyridyl)benzthiazole, PBI = 2-(2′-pyridyl)benzimidazole) Baeyer–Villiger oxidation of cycloketones by dioxygen with cooxidation of aldehydes and peroxycarboxylic acids, including the kinetics on the reactivity of (μ-1,2-peroxo)diiron(III), acylperoxo- and iodosylbenzene-iron(III) species as key intermediates.
