Use of Isotope Ratio Mass Spectrometry (IRMS) Determination (18O/16O) to Assess the Local Origin of Fish and Asparagus in Western Switzerland

Abstract

Here we present the use of isotope ratio mass spectrometry (IRMS) for the detection of mislabelling of food produced in Switzerland. The system is based on the analysis of the oxygen isotope distribution in water (?18O). Depending on the location on the earth, lake or groundwater has a specific isotopic distribution, which can serve as a fingerprint in order to verify whether a product has grown by means of the corresponding water. This report presents specifically the IRMS technique and the results obtained in the origin detection of fish grown in selected Swiss lakes as well as asparagus grown in Valais ground. Strengths and limitations of the method are presented for both cited products; on one hand, the technique is relatively universal for any product which contains significant water but on the other hand, it necessitates a rather heavy workload to build up a database of water ?18O values of products of different origins. This analytical tool is part of the concept of combating fraud currently in use in Switzerland.

Keywords

• Asparagus
• Authentication
• Fish
• Fraud
• Irms