Assessment of the Atmospheric Deposition of Heavy Metals and Other Elements in the Mountain Crimea Using Moss Biomonitoring Technique

Abstract

The atmospheric depositions of heavy metals and other elements on the territory of Crimean Mountains in 2015 was assessed using the moss biomonitoring technique. The neutron activation analysis performed at the installation REGATA of the IBR-2 reactor was used for the determination of the mass fractions of 34 elements (Na, Mg, Al, Cl, K, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Zn, As, Se, Br, Rb, Sr, Sb, I, Cs, Ba, La, Ce, Nd, Sm, Eu, Tb, Yb, Ta, Th, and U). Factor analysis, concentration factors, and enrichment factors were used to reveal possible sources of elements in the mosses. The main contributor to the deposition of elements on the mosses was the weathering of rock materials. The second group of elements included Br and I. The agriculture and marine sources of emissions were found to be important factors of atmospheric Br and I, respectively. The representing maps of the distribution of heavy metals and other elements revealed high levels of elements at the South coast of Crimea and near the city of Simferopol. The comparison of the obtained data with the data of biomonitoring studies performed for other mountain regions showed higher levels of Al, V, Cr, Fe, Ni, and As than in the mosses from Bulgaria, Macedonia, and Norway, but lower than in the mosses from Georgia, Turkey, Romania, and Northern Serbia. The presented results could serve as a basis for future monitoring research.

Keywords

• mosses-biomonitors
• neutron activation analysis
• atmospheric deposition
• heavy metals