One-step synthesis of sandwich-type Cu/graphene/Cu ultrathin foil with enhanced property via electrochemical route

Abstract

A layered structure has a better effect on improving performance of the graphene-reinforced composites due to its unique two-dimensional structure and excellent properties. In this paper, a novel “one-step” electrochemical route was proposed for synthesizing the graphene-reinforced ultrathin copper (Cu) foil with high performance. The process includes: 1) A loose graphene oxide (GO) membrane, was prepared by electrophoresis deposition (EPD), that allows Cu ions passing through; 2) According to the difference of Cu deposition potential on different substrates, a potential step was designed for electrodepositing Cu successively on both sides of the GO membrane, i.e., the bottom Cu layer forms under low over-potential, while the top Cu layer forms under high over-potential. The experimental results show that the foil thickness reaches to as thin as 4–5 μm, and the tensile strength is almost twice as large as that of pure Cu foil. The process is simple, controllable and possible mass production, and expected to further practical applications in fields of Cu clad plate, printed circuit board and lithium-ion battery cathode collector system for saving raw material and also the space. In addition, this work proposes a new idea for preparing the layered composites via electrochemical route.

Keywords

• Electrochemical synthesis
• Ultrathin copper foil
• Graphene
• Tensile strength
• Layered composite