Acta Crystallographica Section E (Aug 2012)

2,3,6,7-Tetramethoxy-9,10-anthraquinone

  • Akira Ohta,
  • Kazuki Hattori,
  • Takeshi Kawase,
  • Takashi Kobayashi,
  • Hiroyoshi Naito,
  • Chitoshi Kitamura

DOI
https://doi.org/10.1107/S1600536812033119
Journal volume & issue
Vol. 68, no. 8
pp. o2587 – o2587

Abstract

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Molecules of the title compound, C18H16O6, are almost planar [maximum deviation = 0.096 (4) Å] and reside on crystallographic centres of inversion. They adopt a conformation in which the Cmethyl—O bonds are directed along the molecular short axis [C—C—O—C torsion angles of −175.3 (3) and 178.2 (3)°]. In the crystal, molecules adopt a slipped-parallel arrangement with π–π stacking interactions along the a axis with an interplanar distance of 3.392 (4) Å. Weak C—H...O interactions link the molecules into sheets parallel to (10-2).