Addition of alkynes and osmium carbynes towards functionalized d π–p π conjugated systems

Shiyan Chen; Longzhu Liu; Xiang Gao; Yuhui Hua; Lixia Peng; Ying Zhang; Liulin Yang; Yuanzhi Tan; Feng He; Haiping Xia

doi:10.1038/s41467-020-18498-2

Nature Communications (Sep 2020)

Addition of alkynes and osmium carbynes towards functionalized d π–p π conjugated systems

Shiyan Chen,
Longzhu Liu,
Xiang Gao,
Yuhui Hua,
Lixia Peng,
Ying Zhang,
Liulin Yang,
Yuanzhi Tan,
Feng He,
Haiping Xia

Affiliations

Shiyan Chen: State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University
Longzhu Liu: Shenzhen Grubbs Institute and Department of Chemistry, Southern University of Science and Technology
Xiang Gao: State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University
Yuhui Hua: State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University
Lixia Peng: State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University
Ying Zhang: State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University
Liulin Yang: State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University
Yuanzhi Tan: State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University
Feng He: Shenzhen Grubbs Institute and Department of Chemistry, Southern University of Science and Technology
Haiping Xia: State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University

DOI: https://doi.org/10.1038/s41467-020-18498-2
Journal volume & issue: Vol. 11, no. 1
pp. 1 – 11

Abstract

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Metal-carbon and carbon-carbon triple bonds are highly unsaturated bonds and their reactions tend to afford cycloaddition intermediates or products. Here, the authors report a new robust reaction on metal-carbon and carbon-carbon triple bonds which affords region- and stereospecific acyclic addition products.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

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