IUCrData (Dec 2021)

rac-(2aS,2a1R,3aR,3a1S,5aS,6aR)-2a-Allyl-2,4-dichloro-2a,2a1,3a1,5a,6,6a-hexahydro-3aH-3-oxadicyclopenta[cd,gh]pentalen-3a-ol

  • Sambasivarao Kotha,
  • Saima Ansari,
  • Naveen Kumar Gupta

DOI
https://doi.org/10.1107/S2414314621012608
Journal volume & issue
Vol. 6, no. 12
p. x211260

Abstract

Read online

The title racemic triquinane, C14H14Cl2O2, is composed of four five-membered rings, one of which is a tetrahydrofuran ring to which an allyl group on one side and a hydroxyl group on the other side are attached. The core of the triquinane unit has a cis–syn–cis configuration. In the crystal, the molecules are linked by pairwise O—H...O hydrogen bonds, generating inversion dimers featuring R22(8) loops.

Keywords